Scalable Oxygen-Ion Transport Kinetics in Metal-Oxide Films: Impact of Thermally Induced Lattice Compaction in Acceptor Doped Ceria Films

نویسندگان

  • Jennifer L. M. Rupp
  • Emiliana Fabbri
  • Jeong-Woo Han
  • Harry L. Tuller
  • Bilge Yildiz
چکیده

Decreasing the dimensions of ionic conductors to the nanoscale has enabled the realization of new electrochemical devices integrated on Si-based and other microsystems. These comprise fast ionic conducting electrolytes for energy-applications such as micro-fuel cells [ 1,2 ] and batteries, [ 3 ] gas conversion/reformation catalysts, [ 4,5 ] sensors, [ 6 ] and for redox-reaction based resistive memories. [ 7,8 ] A key objective for these devices is to simultaneously achieve high device density per chip together with enhanced reaction and transport kinetics. Among various mixed ionic and electronic conducting (MIEC) oxides, doped ceria nano-scale fi lms are of interest for a broad set of these microsystem based applications. [ 6,9,10 ]

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تاریخ انتشار 2014